Rare-Earth Nd Inducing Record-High Thermoelectric Performance of (GeTe) <sub>85</sub> (AgSbTe <sub>2</sub> ) <sub>15</sub>

نویسندگان

چکیده

As a promising midtemperature thermoelectric material with both higher performance and mechanical property, Tellurium Antimony Germanium Silver (TAGS- x ), written as (GeTe) (AgSbTe 2 ) 1- , especially 0.85 0.15 (TAGS-85), has attracted wide attention. Herein, we innovatively use Nd doping to synergistically decrease the carrier concentration optimal level leading enhanced dimensionless figure of merit, zT. Our density-functional theory calculation results indicate that Nd-doping reduced should be attributed enlargement band gap. The optimized in an ultrahigh power factor ~32 μ W cm -1 K -2 at 727 Ge 0.74 Ag 0.13 Sb 0.11 0.02 Te. Simultaneously, lattice thermal conductivity Te retained low ~0.5 K. Ultimately, record-high zT 1.65 is observed This study indicates rare-earth effective boosting TAGS-85 approached via synergistic effect.

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ژورنال

عنوان ژورنال: Energy material advances

سال: 2021

ISSN: ['2097-1133', '2692-7640']

DOI: https://doi.org/10.34133/2021/2414286